Scintillator detector materials...
An ideal scintillator detector material will:
- provide as many electron-hole pairs as possible per unit of gamma-ray
energy
(low Î, where Î
is the average energy needed to create an electron-hole pair);
- have high stopping power for gamma radiation (high density and
atomic number);
- have a response proportional to energy;
- be transparent to light;
- have a short decay time for excited states to allow high count
rates;
- be available in optical quality, in reasonable amounts at reasonable
cost; and
- have a refractive index close to that of glass to allow efficient
coupling to photomultipliers.
Materials which are used for gamma-ray purposes include inorganic
crystals for example: NaI, CsI, CaF2 and
BGO.
For some materials the band gap is large and photons emitted by the
de-excitation of electrons from the conduction band would be outside the
visible range of light. Also the bulk of the material would absorb the
emitted photons before they reach the photomultiplier. Both problems are
solved using an activator. For NaI this is Tl and for CsI it is Tl or
Na.
Scintillator |
Activator |
Abbrev. |
Density
(gcm-3) |
Wavelength
(nm) |
Decay time
(ns) |
Refractive
index |
Rel.
Efficiency (%) |
NaI |
Tl |
NaI(Tl) |
3.67 |
415 |
230 |
1.85 |
100 |
CsI |
Tl |
CsI(Tl) |
4.51 |
550 |
1000 |
1.79 |
45 |
CsI |
Na |
CsI(Na) |
4.51 |
420 |
630 |
1.84 |
85 |
CsI |
|
CsI |
4.51 |
315 |
16 |
1.95 |
5 |
CsF |
|
CsF |
4.64 |
390 |
4 |
1.48 |
6 |
The introduction of small amounts of the activator material as an
impurity produces defect lattice sites which give rise to extra energy
levels within the forbidden band. The ground state of these activator
sites lies just above the valence band and the excited states lie just
below the conduction band. Electrons within the conduction and exciton
band will tend to be captured by the excited activator states. When the
electron de-excites the photon energy released is lower and now in the
visible range.
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